I thought I would start my peppering of this fantastic new subforum with question number one of music theory things that have been at the back of my mind.
The Neapolitan 6(N6) is a very readily discernible chord once you are aware of what you are hearing, typically but not always a 1st inversion of a flatted 2 chord, that resolves to 2nd inversion dominant and then to the tonic. In baroque music it tends to be feel especially prominent when it is occasionally heard, but that did not stop its use into the late romantic.
Once I learned what they were, I started feeling excited about noticing them; typically I had already pinpointed them as colorful points in the pieces they appear in. Although I am sure the likes of Purcell and maybe Lully and Biber were no stranger to them, at the moment, the earliest example that comes to mind is in the fast movement of Georg Muffat's G minor concerto grosso, with a running bass. It's use there is especially striking. And this is as early as 1700 or so.
Am I even thinking early enough?